Effect of core nonsphericity on the entr
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Neil Snider
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Article
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1995
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Elsevier Science
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English
โ 297 KB
The lowering of the entropy of simple liquids due to the nonspherical shape of the repulsive molecular cores was estimated quantitatively from a generalized van der Waals equation. For the liquids considered, the entropy lowering relative to an equivalent hard sphere liquid was found to be in the ra