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On the importance of specific solvent effects in electron trransfer reactions

✍ Scribed by María Luisa Moyá; Francisco Sánchez; John Burgess

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
486 KB
Volume
25
Category
Article
ISSN
0538-8066

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✦ Synopsis

The intramolecular electron transfer reaction within the binuclear complex formed between tetraamminepyrazinecarboxylatocobalt(II1) and aquopentacyanoferrate(I1) ions is studied in various binary aqueous media at different temperatures. Results could not be explained on the basis of a primitive model. Experimental data were fitted by using a multiparameter regression which shows the important role played by specific interactions on reactivity. 0 1993 John Wiley & Sons, Inc.

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