𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the importance of orientation in general base catalysis by carboxylate

✍ Scribed by Richard David Gandour

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
555 KB
Volume
10
Category
Article
ISSN
0045-2068

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

The efficiency of intramolecular general
The efficiency of intramolecular general base catalysis in nonaqeous solvents
✍ Anthony J. Kirby; Koh Lip Lin πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 114 KB

There is good evidence that intramolecular general base catalysis is much less efficient than intramolecular nucleophilic catalysis.' It has recently been suggested' that this is true only for reactions in aqueous solvents, and that in nonaqueous solvents -and perhaps also in enzyme active sites fro

General base catalysis in the decomposit
General base catalysis in the decomposition of N-Cl-Valine in aqueous solution
✍ Ll Abia; X. L. Armesto; M. Canle L.; M. V. GarcΓ­a; M. Losada; J. A. Santaballa πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 565 KB

This article analyzes the kinetics of the decomposition of N-C1-Valine in aqueous solution, which is formed rapidly by chlorination of Valine with sodium hypochlorite. A general-base catalyzed process not yet described is reported. The experimental evidence shows two competitive decomposition paths: