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On the importance of carbocation intermediates in bimolecular nucleophilic substitution reactions in aqueous solution

✍ Scribed by Richard, John P.; Yeary, Paul E.


Book ID
127362276
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
704 KB
Volume
115
Category
Article
ISSN
0002-7863

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Relative rates of nucleophilic reactions
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Benzyl chloride and benzyl acetate were photolyzed in 30% methanol-water mixtures (V/V) at 0Β°C. The photolysis produces benzyl carbocations that react with nucleophiles. The reaction products were analyzed by gas chromatography or liquid chromatography. From the amounts of products the relative valu