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On the identification of the nature of adsorbate interactions

✍ Scribed by A. Datar; S.D. Prasad; L.K. Doraiswamy


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
392 KB
Volume
159
Category
Article
ISSN
0009-2614

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✦ Synopsis


A study of the pressure derivative of the square of the surface coverage is proposed to identify the nature of adsorbate interactions, viz. attractive or repulsive. When interactions are absent maxima in the pressure derivative surface coverage plots occur at a surface coverage of 0.3333. Attractive and repulsive interactions cause positive and negative deviations from this critical value.


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