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On the hydrothermal stability of CuAPSO-34 microporous catalysts for N2O decomposition: a comparison with CuZSM-5

✍ Scribed by B.I. Palella; M. Cadoni; A. Frache; H.O. Pastore; R. Pirone; G. Russo; S. Coluccia; L. Marchese

Book ID: 114046141
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 174 KB
Volume: 217
Category: Article
ISSN: 0021-9517
DOI: 10.1016/s0021-9517(03)00033-2

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Physical stability vs. chemical lability

Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2O. Fig. S1: copper coordination environments in compounds 1–3. See http://www.rsc.org/suppdata/cc/b2/b201501n/

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