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On the high temperature relaxation transitions in cis-1,4-polyisoprene

✍ Scribed by L.V. Sokolova; V.A. Shershnev; Ye.A. Gavrilina

Book ID
118967784
Publisher
Elsevier Science
Year
1983
Weight
482 KB
Volume
25
Category
Article
ISSN
0032-3950

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✍ F. W. H. Kruger; W. J. McGill 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 727 KB

A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (1R)tetramethylthiuram disulfide (TMTD ) -ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mechanism. Electron spin resonance (ESR) spectra on the