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On the Hartree-Fock time-dependent problem

✍ Scribed by A. Bove; G. Da Prato; G. Fano

Publisher
Springer
Year
1976
Tongue
English
Weight
418 KB
Volume
49
Category
Article
ISSN
0010-3616

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On the Hartree-Fock problem
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The Hartrec-Pock problem is i.nvcstig&ed by examining the symmetry properrics of the SC F spin-orbit&. These can be classified ;LS closed-shell, open-sheil or general spin-orbit& accordin:: to the commutation rules satisfied by their one-electron sCF hamiltoniarrs. The effect of symmetry-brcakmg in

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## An cltension of the time-dependent Hartree-Focii approximation to employ a multimnti~ur~ttin Ihrlree-Fock state as reference state has been devefoped-Preliminary multicontigxation time-dependent Hartree-Fock calculations wirh the round state of the Be atom using the configurations Is' and 7~' s

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## Abstract Recent progress in multiconfiguration time‐dependent Hartree–Fock (MC–TDHF) theory is reviewed. The generality of a formalism first put forward by Moccia [Int. J. Quantum Chemistry **8**, 293 (1974)] is emphasized, and illustrative applications are discussed. A calculation of the freque