Results are presented for the effect of periodic boundary conditions on predictions made using the grand canonical ensemble for systems of limited size. A Monte Carlo study of a realistic gas-solid adsorption model and an exact study of the Tonks gas both show that it is necessary for the minor dime
✦ LIBER ✦
On the Grand Canonical Gibbs Ensemble in Euclidean Field Theory
✍ Scribed by R. Gielerak
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 765 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0015-8208
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✦ Synopsis
Abstract
By generalizing the integration by parts formula on the function space, the isomorphism between the general class of selfinteracting Euclidean, Bose fields and classical gases is proven in a nonperturbative way. Rigorous, non‐perturbative derivations of the Mayer equations and Bogoliubov‐Born‐Kirkwood‐Grenn‐Yvone hierarchical equations are given. Expansions of several physical quantities are discussed in terms of the linear graphs, for some general classes of Euclidean fields.
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