On the gas—gas equilibria of polar—non-polar binary mixtures from a polarizable hard-sphere dipole model
✍ Scribed by O.H. Scalise; A.E. Rodriguez; F. Vericat
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 372 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Perturbation theor> is applied to a poiarizsble hard-sphere dipole model mixture. It is shown that for increasing values of the reduced polarizability of the non-polar component . ~_a+gas equilibria of the first and second kind can be described for a polar-non-pu1.u binary mi.rurc. Ilowe\er for the latter case. critical lies do not show the minimum in temperature observed in re.d s\stcms. Cumpariri,on brt\cen thcoretiwl and esperiment.A results are given for He-NH3 and k--Hz0 mi\tures. * Member of Carrera dcl Invcstigsdor Cientitico (CICPBA). ** Member of CarrcrJ dcl Imesdgddor Cientltico (CONKXT).