Chemical properties of butadienyl anions
✍
Sam P. de Visser; Leo J. de Koning; Wim J. van der Hart; Nico M. M. Nibbering
📂
Article
📅
2010
🏛
Elsevier Science
🌐
English
⚖ 571 KB
## Abstract Proton abstraction from 1,3‐butadiene by strong anionic bases in a Fourier‐transform ion‐cyclotron resonance mass spectrometer at relatively low pressure, yields an isomeric mixture of 1‐ and 2‐butadienyl anions. The gas‐phase acidity, Δ__G__°~acid~, of 1,3‐butadiene, associated with pr