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On the Free-Volume Model of the Liquid-Glass Transition

✍ Scribed by Turnbull, David


Book ID
121484878
Publisher
American Institute of Physics
Year
1970
Tongue
English
Weight
475 KB
Volume
52
Category
Article
ISSN
0021-9606

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On free volume of polymers above the gla
✍ S. M. Aharoni πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 331 KB πŸ‘ 2 views

The magnitude of the activation energy for diffusion, ED. is shown to be inversely dependent on the fractional free volume of the polymer above Tg. From the proportionality of ED above and below Tg, the magnitude of El, below T, is also inversely dependent on the free volume in that temperature rang