✦ LIBER ✦

On the free energy changes of a solution in light absorption or emission processes

✍ Scribed by R. Bonaccorsi; R. Cimiraglia; J. Tomasi

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 623 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80273-5

No coin nor oath required. For personal study only.

✦ Synopsis

A simple model to evaluate energy changes in dilute solutions produced by absorption or emission of light is proposed_

The computational scheme exploits some characteristics of the continuum model of liquids and is inserted into ab initio quantum-mechanical programs for isolated molecules. The model is addressed to evaluate changes in thermodynamic properties of the whale solution -while earlier models often consider the solute only -and it presentsa detailed decomposition of the phenomenon into successive steps.

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