On the experimental determination of triplet-triplet extinction coefficients and oscillator strengths
β Scribed by D. Lavalette; R. Bensasson; B. Amand; E.J. Land
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 271 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Oscillator strengths for triplet-triplet transitions in fluid solution are reported. From these resuIts and from a comparison with previous work, experimental support is provided for the constancy of triplet-triplet oscillator strengths under various solvent and temperature conditions.
π SIMILAR VOLUMES
The sentence on p. 277, right column, line 2, should read "Since the fluctuation timeat220Kis ~0.3s [19],... " instead of-?ince the fluctuation rate at 220 K is 20.3 s-i [ 191, . .." so that the cooling rate is indeed 100 K/s, as quoted.
An experimental method involving the temperature dependence of the intensity of trap emission is employed to determine the sign and magnitude of the nearest-neighbor intermolecular interaction matrix element responsible for triplet exciton transport and the number of wave vector states comprising th
The f-value of the Z16Oi band of the free methyl radical W~ZI determined Pxperimentally as (1.2 t 0.2) x 10'2. The rate coefficient for combination was found to be (2.43 h 0.24) x 1013cm3 mal-lsec-1. Rydberg series of the free methyl radical in the far ultraviolet were discovered by \_Herzberg and