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On the existence of tunneling splitting in the dynamic Jahn-Teller effect

✍ Scribed by L. Cianchi; M. Mancini; P. Moeetti


Book ID
112877808
Publisher
Società Italiana di Fisica
Year
1977
Weight
89 KB
Volume
19
Category
Article
ISSN
0375-930X

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We present a theoretical account of the Jahn-Teller (JT) and pseudo-Jahn-Teller (PJT) effects in the photoelectron spectrum of cyclopropane. The PJT interactions between the two JT split X 2 E 0 and Ã2 E 00 electronic states of the cyclopropane radical cation are examined. Nuclear dynamical simulati

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## Abstract By applying the projection operator method it is shown that the complicated Hamiltonian of a __E__ ⊗ ϵ JT system with nonlinear coupling coefficients can be written in terms of two Hamiltonians which are simple to handle and transform according to irreducible representations __E__, __A_