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On the existence and lifetime of the pentaamminecobalt(3+) intermediate in the substitution reactions of (NH3)5CoXn+

✍ Scribed by Jackson, W. G.; McGregor, B. C.; Jurisson, S. S.

Book ID
126305011
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
885 KB
Volume
26
Category
Article
ISSN
0020-1669

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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3βˆ’^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i