𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the exclusion of radical species in the ligand coupling reactions with pentavalent triarylbismuth derivatives

✍ Scribed by Sébastien Combes; Jean-Pierre Finet

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
651 KB
Volume
55
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis

The presence of aryl radical species in the course of arylation reactions with tri and pentavalent organobismuth compounds has been studied by the use of an internal-trap containing reagent: tris(2-allyioxyphenyl)bismuth and its diacetate. The intervention of radical species can be excluded in C-and O-arylation under basic conditions as well as in copper catalyzed O-and N-arylation, as eyelized products were never detected in any of these reactions.

📜 SIMILAR VOLUMES

Influence of the steric hindrance of the
Influence of the steric hindrance of the aryl group of pentavalent triarylbismuth derivatives in ligand coupling reactions
✍ Alexey Fedorov; Sébastien Combes; Jean-Pierre Finet 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 674 KB

Tris(ortho-tolyl) bismuth dichloride derivatives react with nucleophiles under basic conditions to give good to high yields of the C-arylated substrates. Under the same conditions, trimesitylbismuth dichloride affords only poor yields of the C-mesitylated substrates. Similar influence of the substi

ChemInform Abstract: Influence of the St
ChemInform Abstract: Influence of the Steric Hindrance of the Aryl Group of Pentavalent Triarylbismuth Derivatives in Ligand Coupling Reactions.
✍ Alexey Fedorov; Sebastien Combes; Jean-Pierre Finet 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Influence of the Steric Hindrance of the Aryl Group of Pentavalent Triarylbismuth Derivatives in Ligand Coupling Reactions. -Basepromoted reaction of tris(ortho-tolyl)bismuth dichloride with nucleophiles leads to C-arylated products in good yields. Starting from bulkier trimestitylbismuth dichloride

ChemInform Abstract: Metal-dependent Reg
ChemInform Abstract: Metal-dependent Regiospecificity in the Exchange Coupling of the Magnetic Metal Ion with the Free Radical Substituent on Pyridine Base Ligands: Approaches to Photomagnetic Molecular Devices
✍ Noboru Koga; Hiizu Iwamura 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v