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On the exactness of the circular complex

✍ Scribed by Elisabetta Strickland


Book ID
107774610
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
343 KB
Volume
85
Category
Article
ISSN
0021-8693

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We discuss conditions under which extended Koopmans' eigenvalues become exact ionisatlon potentials. Second-order perturbation theory is used to compare with known expressions involving relaxation contributions to the exact resulls. In two-electron systems all the EK elgenvalues are shown to be exac