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On the Empirical Determination of Some Harmonic and Anharmonic Force Constants in Benzene

โœ Scribed by Rashev, S.

Book ID
119959674
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
84 KB
Volume
105
Category
Article
ISSN
1089-5639

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A harmonic oscillator with time-dependent force constant when perturbed by a weak static quartic anharmonicity ti4, 1 small, is shown to generate new features in the dynamics. For weak coupling, both time-dependent perturbation theoretical analysis and near-exact numerical calculations predict that