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On the electrospinning of poly(vinyl alcohol) nanofiber mats: A revisit

✍ Scribed by Pitt Supaphol; Surawut Chuangchote


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
771 KB
Volume
108
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Electrospinning was used to fabricate mats of poly(vinyl alcohol) (PVA; M~w~ = 72,000 Da, degree of hydrolysis β‰ˆ 97.5–99.5) nanofibers from PVA solutions in reverse osmotic water. The effects of solution concentration, applied electrical potential, sonication, and collection distance on morphological appearance and diameters of the as‐spun fiber mats as well as those of the individual fibers were carefully investigated mainly by scanning electron microscopy. The effect of the distance from the center of the as‐spun fiber mat on morphological appearance and diameters of the as‐spun fibers was also investigated. The mechanical integrity of some as‐spun PVA fiber mats was also investigated. At all concentrations and applied electrical potentials investigated, the average diameters of the as‐spun PVA fibers ranged between 85 and 647 nm. The use of sonication to prepare a PVA solution caused the viscosity of the solution to decrease; hence, the observed decrease in the average diameters of the as‐spun fibers and the average diameters of the as‐spun fibers were practically the same throughout the as‐spun fiber mat. Β© 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008


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Effects of the tacticities of poly(vinyl
✍ Hyun Ju Lim; Sung Jun Lee; Han Jo Bae; Seok Kyun Noh; Yong Rok Lee; Sung Soo Han πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 520 KB

## Abstract The effects of tacticities on the characteristics of poly(vinyl alcohol) (PVA) nanowebs prepared by an electrospinning technique were investigated. PVA webs composed of uniform nanofibers with syndiotactic dyad (s‐dyad) contents of 53.5 and 57.3% were successfully obtained with electros