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On the electronic structure of exciplexes in α-(1- OR 2-naphthyl)-ω-N,N-dialkylaminoalkanes

✍ Scribed by A.M. Swinnen; M. Van der Auweraer; F.C. De Schryver

Publisher
Elsevier Science
Year
1985
Weight
816 KB
Volume
28
Category
Article
ISSN
0047-2670

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Substituent effects on the CC bond strength, 18. Stabilization of alkyl radicals by 4-pyridyl, 1-naphthyl or 2-naphthyl substituents in α-position
✍ Herberg, Clemens ;Peyman, Anuschirwan ;Nölke, Margot ;Beckhaus, Hans-Dieter ;Rüc 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB

The formation of the a-substituted radicals 1-9 with the 4pyridyl (?), l-naphthyl(8), and the 2-naphthyl(9) substituent by thermolysis of their dimers 1-3 in solution was investigated. The activation parameters of the homolysis of the central CC bond were obtained from kinetic measurements of the th