On the electronic spectra of nickel(II) polynuclear coordination compounds with pyridine and its derivatives
โ Scribed by M. Andruh; C.I. Lepadatu; Maria Brezeanu
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 223 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0020-1693
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โฆ Synopsis
The electronic spectra of NikC12-type polynuclear coordination compounds are discussed. Considering the in-plane ligand field strength lower than the axial one, the electronic parameters for L = pyridine and 4-benzoyl-pyridine are calculated in the strong field approach and the Angular Overlap Model, taking into account the complete configuration interaction.
๐ SIMILAR VOLUMES
Electronic (298.2 K) and ESR (298 and 77 K) spectra have been measured for Cu(O,CMe), solutions in pyridine derivative (L)\_solvent (S) binary mixtures (L = pyridine, 3chloropyridine, 2chloropyridine; S = n-hexane, n-heptane, cyclohexane, benzene, chlorobenzene, carbon tetrachloride, propylene carbo