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On the effect of chemical radiative collisions

โœ Scribed by V.S. Dubov; L.I. Gudzenko; L.V Gurvich; S.K. Iakovlenko


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
388 KB
Volume
45
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A new type of chemical optically induced reaction is descrl%ed during which the colliding molecules absorb (emit) a photon and simultaneously new molecules are formed. The exchange reaction of a halogen molecule with a noble gas atom and simultaneous photon absorption was analysed. The analysis shows that the absorption coefficient at respective frequencies and atmospheric pressure can reach several reciprocal centimeters.


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The effect of varying the corrugation of the molecule-crystal potential surface in N 2-crystal collisions has been investigated. Increasing the corrugation parameter, /3, increased the average rotational energy transfer. In addition, large values of 13 allow quite marked deviation from mj conservati