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On the Dynamics of Fragment Isomerization in Collision-Induced Dissociation of Peptides

✍ Scribed by Polfer, Nick C.; Bohrer, Brian C.; Plasencia, Manolo D.; Paizs, Béla; Clemmer, David E.

Book ID
127177622
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
325 KB
Volume
112
Category
Article
ISSN
1089-5639

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## Abstract The fragmentation of peptide acetals and peptide diols, corresponding to the hydrated form of the peptide aldehyde, is dominated by the successive losses of two molecules of MeOH and water, respectively. Using model peptides, the fragmentation mechanism, with respect to the loss of meth