On the determination of the molecular weight distribution of poly(dimethyl diallyl ammonium chloride) by ultracentrifugation
✍ Scribed by G. J. Timofejeva; S. A. Pavlova; Ch. Wandrey; W. Jaeger; M. Hahn; K.-J. Linow; E. Görnitz
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 538 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0323-7648
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✦ Synopsis
Abstract
Molecular weight distributions of poly(dimethyl diallyl ammonium chloride) were determined from sedimentation velocity measurements. After a presentation of the experimental basis for the evaluation of distribution curves, molecular weight distribution curves for different samples were discussed and compared with results of solution fractionations and kinetic‐mechanistic investigations.
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The characterization of polyelectrolytes is demonstrated by combination of different ultracentrifuge methods with laboratory as well as technical poly(dially1 dimethyl ammonium chloride) samples. Low speed sedimentation equilibrium in an analytical ultracentrifuge was used to determine the molecular
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