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On the dependence of correlation and relativity: The electron affinity of the copper atom

โœ Scribed by C.M. Marian

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
495 KB
Volume
173
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A one-component spin-free no-pair Hamiltonian has been utilized IO study the influence of relativistic effects on the electron affinity of the copper atom. The calculations show that relativistic and correlation contributions are not independent. Differential relativistic effects are found to be small but tend to increase the electron affinity of Cu.

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