On the decay of the ozonide radical in aqueous alkaline solutions
✍ Scribed by P.K. Bhattacharyya; R.D. Saini
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 302 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
In Illjh pt~otol~s~s oian oxygcnzted aqueous potawum persulphlte solution at pH 12.5 the decal ol the ozomdc ndtcal hx been iound IO ialloa 3/I! order kmcttcs which has been explamcd by reecuons0; t O-= 2 02 and 0; + HO1 -? O2 * OH-
📜 SIMILAR VOLUMES
Photolysis of in strong alkaline solutions in the presence of ϭ S O (pH Ͼ 13) 2 8 molecular oxygen yields ozonide radical ions, These radicals show a complex decay rate Ϫ и O . 3 sensitive to the peroxodisulfate concentration. A reaction mechanism, which includes the reaction of Oи Ϫ and with a rate
The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.