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On the Crystal Structure and Cation Valence of Mn in Mn-Substituted Ba-β-Al2O3

✍ Scribed by Maurizio Bellotto; Gilberto Artioli; Cinzia Cristiani; Pio Forzatti; Gianpiero Groppi


Book ID
112255462
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
158 KB
Volume
179
Category
Article
ISSN
0021-9517

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Systematic studies on the effect of substitutions on the layered manganocuprate Eu 3 Ba 2 Mn 2 Cu 2 O 12 have been conducted. To introduce holes, we have made substitutions of Ca for Eu and/or Sc for Mn, (Eu 3؊x Ca x )Ba 2 (Mn 2؊y Sc y )Cu 2 O 12 . Single-phase compounds are obtained over a fairly w