## Abstract A recently suggested scheme for relating ionisation potentials (__IP__) to excitation energies (__E__) has been applied to pyrazine and 2,6βdimethylpyrazine. The results indicate that in these systems the energy gap (Ξ__E__) between the two lowest lying ^1^__n__,Ο\*βstates is significan
β¦ LIBER β¦
On the correlation between ionization potentials and bond angles in heterocyclic compounds
β Scribed by L.A. Montero; S.A. Medina; A. Paneque; J.R. Alvarez-Idaboy; V.S. Mastryukov
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 488 KB
- Volume
- 249
- Category
- Article
- ISSN
- 0022-2860
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## Abstract An empirical linear correlation exists between nuclear quadrupole resonance frequencies of halogen nuclei (^35^Cl, ^79^Br, ^127^I) and the polarographic reduction potentials in series of organic halides. In terms of electronic structure this is interpreted as a significant relationship