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On the controlled oxidative coupling of glycals: a new strategy for the rapid assembly of oligosaccharides

โœ Scribed by Friesen, Richard W.; Danishefsky, Samuel J.


Book ID
125985376
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
543 KB
Volume
111
Category
Article
ISSN
0002-7863

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A novel glycosylation strategy has been developed whereby a silyl protected thioglycoside can act as both glycosyl donor and acceptor. Taking advantage of a two directional approach in combination with previously reported orthogonal glycosylations, enables highly convergent and versatile assembly of