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On the Construction of the C/D-Ring Systems of Aphidicolin and Stemodin: a Regio- and Stereospecific Synthesis of 17-Noraphidicolaii-16 one and 17-Norstemodan-16-one Preliminary Communication

✍ Scribed by Doriano Bravetti; Rinaldo Marini Bettolot; Alessandro Lupi

Publisher: John Wiley and Sons
Year: 1982
Tongue: German
Weight: 304 KB
Volume: 65
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19820650139

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✦ Synopsis

Abstract

A very simple regio‐ and stereospecific synthesis of 17‐noraphidicolan‐16‐one and 17‐norstemodan‐16‐one by solvolytic rearrangement of suitable bicyclo[2.2.2]‐‐octenyl methanesulfonate is described.

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