𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the Constitutional Stability of η1-Allylmetal Compounds

✍ Scribed by Reinhard W. Hoffmann; André Polachowski


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
134 KB
Volume
4
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


On the stereochemistry of allylmetal-ald
✍ Scott E. Denmark; Eric J. Weber 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 311 KB 👁 1 views

## Abstract The stereochemical course of the intramolecular allylsilane‐aldehyde condensation of **1a** has been investigated. A modest preference for the product arising from a synclinal orientation of double bonds was observed with __Lewis__‐acid catalysts. Cyclization induced by fluoride ion res

On the Stability of Trioxo(η5 -Cyclopent
✍ Dipl.-Chem. Thomas Szyperski; Dr. Peter Schwerdtfeger 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB

C-C bond. When the hydrogens are bent inward, they approach the nodes and their coefficients decrease. This means that CH bonding character is diminished. The opposite is true when the hydrogens are bent back. Not only additional CH but also enhanced CC bonding develops. The energy of the azu orbita