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On the conformation of the cyclopropyl cation

✍ Scribed by D.B. Ledlie; W. Barber; F. Switzer


Book ID
104243820
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
173 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis


Our previous studies with several tricyclic halocyclopropanee indicate that in these systems "full-fledged" cyclopropyl cations are not reaction intermediates; rather, a partially opened species is implicated which begins to resemble a perpendicular ally1 cation.L Examination of molecular models demonstrates that


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