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On the configuration and conformation of oxyallyls in medium and large rings

✍ Scribed by JM Goodman; HMR Hoffmann; JG Vinter

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
278 KB
Volume
36
Category
Article
ISSN
0040-4039

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13C NMR spectroscopy can be used to determine the configuration of methyl-substituted double bonds in medium-and large-ring terpenoid natural products. A number of examples from our investigations in the germacranolide field are presented, and clearly show that if the resonance for the vinylic methy