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On the complex nature of the reaction between potassium and alkyl halides; rearrangement and fragmentation reactions of alkyl potassium compounds.

✍ Scribed by R.A. Finnegan

Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
280 KB
Volume
3
Category
Article
ISSN
0040-4039

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✦ Synopsis

Sodium alkyle are routinely prepared in good yield by reaction of the metal with an alkyl halide (Equation 1, 'M = Na). (1) RX t 2M _______) RM + MX These preparations are carried out by slowly adding the halide to a suspension of finely divided metal in a hydrocarbon medium under conditions of high speed stirring, a reaction temperature of -loo, and under an inert atmosphere. 1 In addition, it is ' (a) A.

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## Abstract The kinetics of tartaric acid oxidation by peroxodisulphate ion has been studied to elucidate the mechanism of oxidation. Uncommon to many peroxodisulphate reactions it shows a variation in order. It is found to progress bimolecularly in the beginning and unimolecularly till completion.