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On the Complex Formation of Tris-(dipivalomethanato)-europium with Pyridine

✍ Scribed by H. Huber; J. Seelig

Publisher: John Wiley and Sons
Year: 1972
Tongue: German
Weight: 221 KB
Volume: 55
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19720550119

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✦ Synopsis

Abstract

The complexation of the shift reagent tris‐(dipivalomethanato)‐europium with pyridine in deuteriochloroform has been studied by means of ^1^H‐NMR. Shift parameters S = 28.0, 9.9, and 9.2 ppm respectively for pyridine protons 2, 3 and 4 are obtained. The results indicate that the shift reagent complexes a single pyridine molecule with an association constant K~1~ > 100 mole^−1^l.

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