On the burst of branched polymer melts during inflation
β Scribed by Henrik Koblitz Rasmussen; Kaijia Yu
- Publisher
- Springer-Verlag
- Year
- 2007
- Tongue
- English
- Weight
- 390 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0035-4511
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π SIMILAR VOLUMES
The melt viscosity (,Ta) is calculated for polydisperse branched polymers by two methods: (1) by extending Graessley's theory of melt flow of polydisperse linear chains to include the effects of branching, and (2) by empirical deduction leading to the relation (~TB;'/('/L)= [(Ss:)w/ (SL2)~,] w2 for
Based on the free volume concept and the equation by Doolittle, an empirical equation is offered for the flow activation energy, E\*, for polymer melts for the range of over 150Β°C above glass transition temperature, Tg. This E\* represents the temperature coefficient of viscosity for the Newtonian r