On the bromination of 1-bromo-1-(adamantyl-1)ethane
β Scribed by F.N. Stepanov; V.D. Suchoverchov; A.G. Yurchenko
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 105 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract magnified image We found that 1β(2βadamantyl)β3β__tert__βbutylaziridinβ2βone (**5a**) is unstable. It slowly decomposes at room temperature, although detectable by IR spectroscopy (1840 cm^β1^ band in CCl~4~). On the other hand, a closely related analogue, 1β(2βadamantyl)β3β(1βadamanty
Ab initio optimizations at the HF/6-31G level and single-point calculations at the MP2/6-31G\*\*//6-31G level were performed on ethane-1,1-diol and ethane-1,1,2-triol. Their conformational properties are discussed in terms of the anomeric effect, gauche effect and internal O-H interactions. The resu