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On the breathing effect of a metal–organic framework upon CO2 adsorption: Monte Carlo compared to microcalorimetry experiments

✍ Scribed by Ramsahye, Naseem A.; Maurin, Guillaume; Bourrelly, Sandrine; Llewellyn, Philip L.; Loiseau, Thierry; Serre, Christian; Férey, Gérard

Book ID
121206790
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
250 KB
Volume
31
Category
Article
ISSN
1359-7345

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An Explanation for the Very Large Breath
An Explanation for the Very Large Breathing Effect of a Metal–Organic Framework during CO2 Adsorption
✍ C. Serre; S. Bourrelly; A. Vimont; N. A. Ramsahye; G. Maurin; P. L. Llewellyn; M 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 483 KB 👁 1 views

Breathing is usually associated with life. However, such a reversible process can also, intriguingly, be associated with solidstate materials that have the ability to 'breathe' when exposed to an external stimulus (e.g., pressure, temperature, light, gas, or solvent adsorption), sometimes with large