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On the behaviour of exchange in restricted hartree-fock-roothaan calculations for periodic polymers

✍ Scribed by Lucjan Piela; Jean-Marie André; Joseph G. Fripiat; Joseph Delhalle


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
806 KB
Volume
77
Category
Article
ISSN
0009-2614

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✦ Synopsis


Analysis of the restrIcted Hartree-Fock (RHF) ewhange potentml IS presented. In po1ymer.c chams, a reIatmn between the short-rangeness of the exchange and the ener_w gap IS observed. In metalhc systems, the exchange IS of long-range and correlation corrections are expected to be unportant The vahdlty of RHF solutions III metalhc sltuatlons IS oonsrdered