On the asymptotic behavior of the electron affinity of clusters of rare-gas atoms
โ Scribed by IT Iakubov; VV Pogosov
- Book ID
- 108390324
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 435 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0042-207X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The electron affinity (EA) of the Cu atom IS computed uung large ST0 and CT0 basss sets at several levels of correhfion The best computed value IS 1 00 eV compared with the expenmentalvalue of 1.326 eV Rehtlvlstrc effects shghtlh decresse the EA.
Rare 9s ad&tom dipoles are shown to be small and uvxpnble of explaining observed uork function changes Three-body dispersion forces yield v;tlues consistent xrith the reduction in the adatom p.dr potentials; contrtbutions from adatom dipoles are negligible.
The mcltin~ transition of small clusters cornposed of 13 particIcs intcractinp via the Lennard-Jones 6-11 potential has been investigated by mans of estensive aletrapolis hlonte Carlo sinu&tions. TIie results indicate that \vhereas ttlc clusrcr evaporates in vacuum, in a confined pore the cluster un