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On the aromaticity of phospholes and arsoles

✍ Scribed by Epiotis, Nicolaos D.; Cherry, William


Book ID
126286836
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
641 KB
Volume
98
Category
Article
ISSN
0002-7863

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## Abstract Calculations on phosphole systems using the G3MP2B3 model chemistry show that the phosphorus lone pair is critical to the system's aromaticity. Protonation of the lone pair results in antiaromatic molecules as measured by homomolecular homodesmotic reactions. Attempts to separate out ef