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On the adsorption voltammetry of the boron-Beryllon III system: Part II. Mechanism of the electrochemical reduction of Beryllon III and its complex with B(III) in acetate buffer

โœ Scribed by Wenrui Jin; Kui Jiao; H. Metzner


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
661 KB
Volume
5
Category
Article
ISSN
1040-0397

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## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0โ€“50 (v/v) % MeOH) at 15.0โ€“35.0ยฐC and I = 0.10 mol dm^โˆ’3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ ยท CoOCOCO~2~Ni]^3+^ in wh