On the Acids Derivable from the Cyanides of the Oxy-Radicals of the Di- and Tri-Atomic Alcohols
โ Scribed by Simpson, M.
- Book ID
- 120129076
- Publisher
- The Royal Society
- Year
- 1864
- Weight
- 276 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0365-0855
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๐ SIMILAR VOLUMES
## Abstract Four ligands, which can be considered as diโ [both symmetric (L^1^) and asymmetric (L^2^)], triโ (L^3^), and tetraacetate (L^4^) derivatives of bis(aminomethyl)phosphinic acid (L^0^) have been synthesized and their complexation equilibria involving Mg^2+^, Ca^2+^, Ni^2+^, Cu^2+^, Zn^2+^
Reaction of methanesulfonyl cyanide or p-toluenesulfonyl cyanide with carbon radicals generated from the acyl derivatives of N-hydroxy-2-thiopyridone gives the corresponding nitriles in high yield. A mechanistic scheme is suggested. There are many synthetic applications of carbon radicals generated