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On the absence of stereoselectivity in the catalytic oxidation of alkenes with a surface-bound metalloporphyrin-peptide conjugate

✍ Scribed by G.Richard Geier III; Terry P. Lybrand; Tomikazu Sasaki


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
732 KB
Volume
55
Category
Article
ISSN
0040-4020

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Catalytic oxidation of alkenes with a su
✍ G. Richard Geier III; Tomikazu Sasaki πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 843 KB

A novel surface-bound metalloporphyrin-peptide conjugate was prepared and used to catalytically oxidize alkenes in the presence of iodosylbenzene. The catalyst was found to oxidize a number of alkene substrates in good yield under a variety of reaction conditions. Comparison to control experiments u