On Systematics in the 19F Electric Hyperfine Interactions
β Scribed by Michael Frank
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 853 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0015-8208
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π SIMILAR VOLUMES
A recently published theory of electric field effects on electron spin w Ε½ .x resonance hyperfine couplings Phys. Ref. Lett. 79, 379, 1997 is extended to nuclear quadrupole coupling. With the use of the ab initio coupled HartreeαFock approach and augmented Sadlej basis set, results are obtained for
F hyperfine splitting due to a solitary fluorine atom has been observed in complexes of amines with CuF2 and Cu(BF4)2. Vibronic coupling is postulated to explain this hyperfine splitting. We have investigated the effect of a series of anions, i.e. F-, BF4-, Cl-, Br-and NO3-, on the EPR spectra of cu