On studies of oxide solubilities in melts based on alkaline halides

✍ Scribed by V.L. Cherginets

• Publisher: Elsevier Science
• Year: 1997
• Tongue: English
• Weight: 976 KB
• Volume: 42
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/s0013-4686(97)00031-5

✦ Synopsis

Studies

of oxide solubilities (methods and results) in molten alkaline chlorides are considered. The scatter of literature data on oxide solubilities in molten KCI-NaCl has been explained by the effect of crystal grain sizes on their solubilities according to the Ostvald-Freindlich rule. Author's results of systematic oxide solubilities' studies in molten alkaline halides (KCI-NaCl, CsCl-KCl-NaCl, CsBr-KBr, CsI) are considered. Oxide solubilities in molten alkaline halides (pP) have been found to vary linearly with corresponding cation radii; such plots might be proposed for estimations of oxide solubilities in molten alkaline halides. 0 1997 Elsevier Science Ltd Key iv&s: oxide solubilities, alkaline halides, molten salts.