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On So-Called Concentration and True Thermodynamic Equilibrium Constants in Solution

✍ Scribed by V. P. Vasil'ev


Book ID
111607821
Publisher
SP MAIK Nauka/Interperiodica
Year
2004
Tongue
English
Weight
21 KB
Volume
30
Category
Article
ISSN
1070-3284

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## Abstract The origin of the difference between the equilibrium (affinity) constants of ligand–receptor binding in bulk solution and at a solid‐solution interface is discussed in terms of Gibbsian interfacial thermodynamics. It results that the difference is determined by the surface work that the