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On oscillographic polarography of non-ionic tensides

✍ Scribed by Per Holmqvist


Book ID
104148948
Publisher
Elsevier Science
Year
1972
Weight
218 KB
Volume
39
Category
Article
ISSN
0022-0728

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✦ Synopsis


The adsorption of surface-active substances at electrodes has been extensively reviewed 1-4. While developing analytical methods for non-ionic tensides it was found that these substances when adsorbed at a mercury electrode exhibited capacity effects which could not be fully explained. The present communication attempts to describe the features of general structure of the double layer for this group of substances.


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The adsorption of dodecylamine hydrochloride (DDAHC) and polyoxyethylene (20) sorbitan monolaurate (Tween-20) from their single aqueous solutions and from DDAHC-Tween-20 mixed binary solutions on calcium carbonate at 20°C has been investigated. The results show that individual cationic surfactants