On-line coupling of capillary isotachophoresis and zone electrophoresis for the assay of phenolic compounds in plant extracts
✍ Scribed by Marek Urbánek; Marie Pospíšilová; Miroslav Polášek
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 119 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0173-0835
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The on-line coupling of capillary zone electrophoresis with mass spectrometry (CZE-MS) for the separation of enantiomers is hampered by the presence of nonvolatile chiral selectors such as cyclodextrins in the separation buffer. This problem can be overcome by use of the partial filling technique wh
A novel microelectrospray interface for the on-line coupling of capillary-zone electrophoresis (CZE) and mass spectrometry is described. The outlet of the fused-silica CZE capillary is tapered and serves as the microspray tip. The spray does not contain a sheath flow nor does the capillary tip conta